Photoreaction of S-butyl 3-methoxy-2-butenethioate. Competitive 1,5-methyl migration and O-demethylation.
スポンサーリンク
概要
- 論文の詳細を見る
Irradiation of <I>S</I>-butyl (<I>Z</I>)-3-methoxy-2-butenethioate (<B>1Z</B>) gave the 1,5-methyl migration product <B>2</B> and the <I>O</I>-demethylation product <B>3</B>. The photo-1,5-methyl migration occured competitively with the <I>O</I>-demethylation from the π, π<SUP>*</SUP> excited triplet state of <B>1Z</B>. The migration product <B>2</B> underwent the secondary photoreaction to <B>3</B> in a nondegassed benzene solution.
- 公益社団法人 日本化学会の論文
著者
-
Hasegawa Tadashi
Department Of Cardiovascular And Thoracic Surgery Hakodate Municipal Hospital
-
Yoshihara Nobutoshi
Department Of Chemistry Tokyo Gakugei University
-
Iwasaki Kazuhiko
Department of Chemistry, Tokyo Gakugei University
関連論文
- Periosteal chondrosarcoma with microscopic cortical invasion
- Case report of a focal nodular hyperplasia-like nodule present in cirrhotic liver
- Analysis of CHOP rearrangement in pleomorphic liposarcomas using fluorescence in situ hybridization
- Pleomorphic phenotypes of gastrointestinal stromal tumors at metastatic sites with or without imatinib treatment
- Author reply
- Low-grade fibromyxoid sarcoma arising in the big toe
- Repair of Ventricular Septal Perforation with Asymmetrical Conical Patch Exclusion
- Primitive Neuroectodermal Tumor of the Pancreas
- GM3 synthase gene is a novel biomarker for histological classification and drug sensitivity against epidermal growth factor receptor tyrosine kinase inhibitors in non-small cell lung cancer
- A Case of Non-Hodgkin's Lymphoma and Invasive Thymoma Treated with R-CHOP Therapy