Photochemical reaction of ethyl 3-oxo-2,4-diphenylbutanoate.
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概要
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Irradiation of ethyl 3-oxo-2,4-diphenylbutanoate in hexane gave the products formed by recombination of the radicals (Ph–\dotCH<SUB>2</SUB> and/or Ph–\dotCH–CO<SUB>2</SUB>Et) resulting from decarbonylation, together with small amounts of 1,2-diphenylethanol and ethyl α-hydroxyphenylacetate, whereas in benzene no 1,2-diphenylethanol was found. Under oxygen an increased amount of ethyl α-hydroxyphenylacetate and no radical recombination products were observed.
- 公益社団法人 日本化学会の論文
著者
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Yoshioka Michikazu
Department Of Chemistry Faculty Of Science Saitama University
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Osawa Haruhiko
Department of Chemistry, Saitama University
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Fukuzawa Shinji
Department of Chemistry, Saitama University
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