Benzylphenol derivatives as antioxidants for autoxidation of tetralin.

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概要

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• A series of 4-benzylphenols, 2-methyl-4-benzylphenols, 4-methyl-2-benzylphenols and 4-methoxy-2-benzylphenols have been prepared and evaluated as antioxidants for tetralin at 60 °C by means of an oxygen-absorption method. Very good activities have been observed with a series of 4-methoxy-2-benzylphenols. The electrochemical oxidation potentials of these compounds were determined using linear-sweep voltammetry. The antioxidative activities were found to correlate with both the <SUP>13</SUP>C NMR chemical shifts (δ) of the <I>ipso</I>-carbon of the OH substituent and their peak potentials (<I>E<SUB>p</SUB></I>).

• 公益社団法人 日本化学会の論文

著者

• Nishiyama Tomihiro

  Department Of Applied Chemistry

• Yamada Fukiko

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

• Yamamura Tatsuo

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

• Suzuura Yasuki

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

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