The Stereochemistry of 5-Substituted 2-Oxo-3-aryl-1,2,3-oxathiazolidines

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概要

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• New six 2-oxo-3-aryl-5-methyl-1,2,3-oxathiazolidines and six 2-oxo-3-aryl-5-chloromethyl-1,2,3-oxathiazolidines have been prepared in good yields by the reactions of <I>N</I>-sulfinylanilines with propylene oxide and epichlorohydrin respectively in the presence of catalysts. The compounds obtained exist in isomeric <I>cis</I> and <I>trans</I> forms at the S=O bond. The configurations of their stereoisomers were discussed by means of NMR.

• 公益社団法人 日本化学会の論文

著者

• Nishiyama Tomihiro

  Department Of Applied Chemistry

• Yamada Fukiko

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

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