Rate coefficient for H+C2H2..LAR..RAR..C2H+H2.
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概要
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The rate coefficient expressions <I>k</I>=10<SUP>13.78</SUP> exp(−99 kJ/<I>RT</I>) cm<SUP>3</SUP> mol<SUP>−1</SUP>s<SUP>−1</SUP> for H+C<SUB>2</SUB>H<SUB>2</SUB>→C<SUB>2</SUB>H+H<SUB>2</SUB> and <I>k</I>=10<SUP>13.05</SUP> exp(−12 kJ/<I>RT</I>) cm<SUP>3</SUP> mol<SUP>−1</SUP>s<SUP>−1</SUP> for C<SUB>2</SUB>H+H<SUB>2</SUB>→H+C<SUB>2</SUB>H<SUB>2</SUB> were proposed after correcting for errors in previously reported data analyses of shock tube data on C<SUB>2</SUB>H<SUB>2</SUB> pyrolysis.
- 公益社団法人 日本化学会の論文
著者
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Koike Tohru
Department Of Applied Chemistry National Defense Academy
-
Morinaga Kihei
Department of Chemistry Defense Academy
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Gardiner William
Department of Chemistry, University of Texas
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Tanzawa Tsuneo
Department of Chemistry, University of Texas
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