Infrared spectrum of dichloroborane produced by CO2 laser enhanced reaction.
スポンサーリンク
概要
- 論文の詳細を見る
Infrared spectra of HBCl<SUB>2</SUB> and DBCl<SUB>2</SUB> produced by a TEA CO<SUB>2</SUB> laser enhanced reaction of BCl<SUB>3</SUB> and H<SUB>2</SUB>/D<SUB>2</SUB> have been observed by an FT-IR spectrometer at a resolution of 0.12 cm<SUP>−1</SUP>. A detailed analysis has been carried out for the ν<SUB>1</SUB> band of HBCl<SUB>2</SUB> to obtain the precise molecular parameters, and they are compared with the microwave data. The fundamental frequencies other than the ν<SUB>3</SUB> band have all been determined. These frequency data combined with the results of an <I>ab initio</I> MO calculation have yielded the general symmetry force field through a least squares method. Some characteristic features on the CO<SUB>2</SUB> laser reaction of BCl<SUB>3</SUB> and H<SUB>2</SUB> are also discussed.
- 公益社団法人 日本化学会の論文
著者
-
Kondo Shigeo
National Chemical Laboratory for Industry, Tsukuba Research Center
-
Takeo Harutoshi
National Chemical Laboratory for Industry, Tsukuba Research Center
-
Takeo Harutoshi
National Chemical Laboratory for Industry
-
Matsumura Chi
National Chemical Laboratory for Industry
-
Lee Kuk-Haeng
National Chemical Laboratory for Industry, Tsukuba Research Center
-
Kondo Shigeo
National Chemical Laboratory for Industry
関連論文
- Estimation of Total Infrared Intensities of Fluorinated Ethyl Methyl Ethers
- Influence of Gas Flow Conditions on Cluster Size Distribution in the Gas Evaporation Method
- Infrared intensities in methyl chloride. III. Improvement of the anharmonic force field and the analysis of the overtone and combination band intensities.
- Infrared intensities in methyl chloride. II. Binary overtone and combination bands.
- Dipole moments of molecules containing single chlorine atoms.
- The microwave spectrum of dichlorodifluoromethane.
- Infrared spectrum of dichloroborane produced by CO2 laser enhanced reaction.
- The microwave spectra, molecular structures, and quadrupole coupling constants of methyltrichlorosilane and trichlorosilane.
- The microwave spectrum, structure, quadrupole coupling constants, and barrier to internal rotation of methyldichlorosilane.
- Infrared intensities in methyl chloride. I. The fundamental bands.