Solubility of tris(acetylacetonato)chromium(III) in aqueous alcohol mixtures.
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概要
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From the temperature dependence of the solubility of tris(acetylacetonato)chromium(III) in aqueous <I>t</I>-butyl alcohol mixtures and in aqueous methanol mixtures, thermodynamic parameters of the solution were calculated. The solubility and these parameters in aqueous <I>t</I>-butyl alcohol mixtures could be explained qualitatively by the cavity formation terms of the scaled particle theory. It was suggested that tris(acetylacetonato)chromium(III) is in water microphases at <I>X</I><SUB>BuOH</SUB>≤0.04 and in <I>t</I>-butyl alcohol microphases over this region.
- 公益社団法人 日本化学会の論文
著者
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Yamamoto Manabu
Department of Applied Electronics, Tokyo University of Science, 2641 Yamasaki, Noda, Chiba 278-8510, Japan
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Yamamoto Manabu
Department of Chemistry, Faculty of Science, Hiroshima University
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