Preparation and some reactions of diarylgermylenedialkali metals.
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概要
- 論文の詳細を見る
The reactions of diarylgermanes with alkali metals in HMPA/THF or THF were found to give the corresponding diarylgermylenedialkali metals in high yields. Diphenylgermylenedipotassium reacted with aryl halides or carbonyl compounds to give reduction products predominantly. With alkyl halides, diphenylgermylenedipotassium gave mainly substitution products.
- 公益社団法人 日本化学会の論文
著者
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Mochida Kunio
Department Of Chemistry Faculty Of Science Gakushuin University
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Matsushige Naoki
Department of Chemistry, Faculty of Sciences, Gakushuin University
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Hamashima Mari
Department of Chemistry, Faculty of Sciences, Gakushuin University
関連論文
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- Radical Cation of Dodecamethylcyclohexagermane Generated by Pulse Radiolysis
- Radical Anions of Oligogermanes, Me(Me_2Ge)_nMe(n=2, 3, 5, and 10)Generated by Pulse Radiolysis
- Synthesis and Photochemical Reactions of Polystannanes
- Mobilities of Charge Carriers in Dendrite and Linear Oligogermanes by Flash Photolysis Time-resolved Microwave Conductivity Technique
- Structures and Ionization Energies of Some Bis- and Tris(3,4-dimetala-1-butyne-1,4-diyl)s Containing Group 14 Elements as Key Metal Atoms: Tetragermacycloocta-1,5-diyne, Hexasilacyclododeca-1,5,9-triyne, Hexagermacyclododeca-1,5,9-triyne, and Related Comp
- Photoinduced Electron Transfer from Tetraphenyl-Substituted 1,2-Digermacyclohexa-3,5-dienes and Related Compounds to C_
- Nonlinear Optical Susceptibility of Oligo- and Polygermanes
- Preparation of Branched Oligogermynes and Their Micropatterning by Ultraviolet Irradiation
- Photoinduced Electron Transfer From Cyclic Organogermanium Compounds to C_ Studied by Laser Flash Photolysis
- He I Photoelectron Spectra of Permethylated Polygermanes
- Thermal Ring Contraction of 1,2-Digermacyclohexadienes Coordinated with Iron Tricarbonyl Fragment
- Studies of Germanium-Platinum Bonds in Bis(aryl-substituted Germyl)platinum Complexes by Laser Flash Photolysis and Chemical Trapping Experiments
- Preparation and Structural Characterization of Bis[tris(trimethylsilyl)-germyl]zinc, [(Me_3Si)_3Ge]_2Zn
- Preparation and Characterization of Tris(trimethylsilyl)germylzinc Chloride and Bis[tris(trimethylsilyl)germyl]zinc
- Chlorinative Cleavage of Digermoxanes Initiated by Photo-induced Electron Transfer
- Cleavage of a p-Cyanobenzyl Group from Protected Alcohols, Amines, and Thiols Using Triethylgermyl Sodium
- Synthesis and Ring-opening of 1, 2-Digerma[2]ferrocenophane Catalyzed by Palladium or Platinum Complexes
- Tetracyanoethylene-induced Chlorinative Cleavage of Permethylated Oligogermanes with Polyhalomethanes
- Synthesis, Structural Characterization, and Photolysis of Dibenzodehydro[16]annulenes Containing E-E σ Bonds (E = Si and Ge)
- Photochemical Isomerization of 1-Germa-2,4-cyclohexadienes
- Preparation and Properties of 3,4,7,8-Tetragermacycloocta-1,5-diyne and Related Compounds
- Synthesis and Kaleidoscopic Reactivities of Bis(tritolylgermyl)bis(dimethylphenylphosphine)platinum(II)
- Preparation, Structural Characterization, and Reactivities of (Digermanyl)lithium. Its Application to the Synthesis of Bis(1,1-diphenyl-2,2,2-trimethyldigermanyl)platinum(II)
- Cyclization of 1,2-Disilacyclohexa-3,5-dienes Initiated by Electron Transfer Reactions with TCNE
- Ring Contraction of 1,2 - Digermacyclohexa - 3,5 - dienes Initiated by Electron Transfer Reactions with TCNE
- Reactivities of Triethylgermylborate in Methanol
- A Useful Palladium Catalyst for Addition of Ge-Ge Bonds to Alkynes
- Synthesis of Hexakis(alkygermasesquioxane)s from Alkyl(chloro)ethoxygermanes and Their Formation Mechanism
- Palladium-Catalyzed Addition of Tetragermetanes to Alkynes
- Formation of Unique Platinum-Silyl Complexes by the Reactions of a Zero-valent Platinum Complex with Various Trisilanes
- On the mechanism of uncatalyzed reduction of triphenylmethyl chloride with triethylgermane.
- The reaction of calcium atoms with group 4B catenates, Me3E-E'Me2R(E, E'=Si, Ge, Sn; R=Me, Cl).
- Preparation of organocalcium halides using calcium ultrafine particle.
- Preparation and some reactions of diarylgermylenedialkali metals.
- Chemistry of germanium atoms. II. Reactions of thermally evaporated germanium vapor with organic halides.
- A correlation of electrochemical oxidation and ionization potentials of group 4B dimetals.
- Stereochemistry of the reactions of trimethylgermyl anions with 4-t-butylcyclohexyl derivatives.
- Photochemical Reactions of Aryl-Substituted Digermanes through a Pair of Organogermyl Radicals.
- Stereochemistry of a chiral germyl radical in the reaction of carbon tetrachloride.
- The thermal reactions of allyl-substituted germyl radicals.
- Reactions of trialkylstannane anions R3Sn- with arylstannanes ArSnR'3.
- Chemistry of germanium atoms. III. Reactions of thermally evaporated germanium vapor with hydrogermanes.
- Activation of C-H bonds of heterocyclic and alicyclic compounds using calcium atoms.
- Chemistry of germanium atoms. V. Deoxygenation of carbonyl compounds by germanium vapor(atom).
- ESR studies of the reaction of the calcium atom with substituted benzene vapors.
- Photochemical Reactions of Vinyl-, Styryl-, and Benzyl-Substituted Digermanes.