Reaction of hydroxide ion with electron acceptors in dimethyl sulfoxide.
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概要
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In dimethyl sulfoxide, the reaction of hydroxide ion with several electron acceptors—iodine, tetracyanoquinodimethan, Nitro Blue Tetrazolium chloride, 2,3,5-triphenyltetrazolium chloride, anthraquinone, and benzophenone—gave reaction products identical to those obtained by the reaction of these electron acceptors with electron donors. The reaction pathways of these electron acceptors were found to be composed of successive one-electron reactions similar to the electrochemical reduction of these electron acceptors. These results indicate that hydroxide ion acts as a reductant in dimethyl sulfoxide.
- 公益社団法人 日本化学会の論文
著者
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Umemoto Kisaburo
Department of Chemistry Faculty of Science Kyoto University
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OKAMURA Nobuyuki
Department of Cardiovascular Surgery, Showa General Hospital
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Okamura Nobuyuki
Department of Pure and Applied Sciences, College of Arts and Sciences, The University of Tokyo
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