Thermodynamic studies of thallium halide formation in nonaqueous solvents.

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概要

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• The differences in the order of stability among halide ions for metal halogeno-complexes in nonaqueous solvents and water are examined by means of the thermodynamic constants for the formation of thallium halides of transfer from water to <I>N</I>,<I>N</I>-dimethylformamide (DMF) and propylene carbonate (PC). The thermodynamic constants for the formation of thallium halides were calculated from the solubility products of thallium halides. The differences in the order of stability for thallium halides were found to be dependent mainly on the enthalpy changes for the formation of thallium halides of transfer from water to DMF and PC, while the enthalpy changes of transfer for thallium halides are themselves largely influenced by the enthalpy changes for halide ions of transfer from water to DMF and PC.

• 公益社団法人 日本化学会の論文

著者

• Sasaki Yukio

  Tokyo Institute Of Polytechnics

• Umemoto Kisaburo

  Department of Chemistry Faculty of Science Kyoto University

• Matsuura Niro

  Department of Chemistry, College of General Education, The University of Tokyo

• Sasaki Yukio

  Tokyo Institute of Photographic Technology

• Takizawa Masao

  Tokyo Institute of Polytechnics

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• Thermodynamic studies of thallium halide formation in nonaqueous solvents.

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