Preparation and reaction of optically active organotransition metal complexes. II. Preparation and photoracemization of optically active (1-cyanoethyl)cobaloxime complexes coordinated with various axial ligands.
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概要
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Optically active (1-cyanoethyl)cobaloxime complexes coordinated with various pyridines, phosphines and amines etc. as axial ligands were prepared and their photoracemization rates were measured in a solution state. It was found that the steric factor, rather than the electronic, of the axial ligand controlled, predominantly, the rate of Co–C bond homolysis in these alkylcobaloximes.
- 公益社団法人 日本化学会の論文
著者
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Takeuchi Seiji
Niigata College Of Pharmacy
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OHGO Yoshiaki
Niigata College of Pharmacy
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Baba Shoe
Niigata College of Pharmacy
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Baba Shoe
Niigata Academy of Medical Technology
関連論文
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- Chiral Lattice-Controlled Asymmetric Photoisomerization of (2-Cyanoethyl)cobaloximes in the Solid State
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- The SmI_2 Mediated Cross-Coupling Reaction of Aldehydes with α-Diketones in Their Aqueous Forms
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