The molecular structure of (+)589-.BETA.2-(3-methyl-2-iminobutanoato)((2S,10S)-4,8-diazaundecane-2,10-diamine)cobalt(III) perchlorate: .ALPHA.-Imino acidato complex.
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概要
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The crystal structure of (+)<SUB>589</SUB>-β<SUB>2</SUB>-(3-methyl-2-iminobutanoato)((2<I>S</I>,10<I>S</I>)-4,8-diazaundecane-2,10-diamine)cobalt(III) perchlorate has been determined by the single-crystal X-ray diffraction method. The complex ion adopts <I>Λ</I>-β<SUB>2</SUB> configuration, and it has the Co–N(imine) bond length of 1.90 Å, which is shorter than the Co–N(amine) bond lengths. The chelate ring of the 2-imino carboxylato is planar.
- 公益社団法人 日本化学会の論文
著者
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YAMAGISHI Takamichi
Department of Industrial Chemistry, Faculty of Engineering, Tokyo Metropolitan University
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Hida Mitsuhiko
Department of Industrial Chemistry, Faculty of Engineering, Tokyo Metropolitan University
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