Palladium-promoted transformation of .BETA.-amino ketones to enaminones.
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概要
- 論文の詳細を見る
The reaction of β-amino ketones with bis(acetonitrile)dichloropalladium(II) in the presence of triethylamine gives the corresponding enaminones regioselectively. The cyclic β-amino ketones can be converted into the corresponding exocyclic enaminones. The enaminones thus obtained are versatile synthetic intermediates. The reaction of (E)-enaminones with organocuprates gave the corresponding (E)-α,β-unsaturated ketones.
- 公益社団法人 日本化学会の論文
著者
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Mitsue Yo
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Murahashi Shun-ichi
Department Of Applied Chemistry Okayama University Of Science
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MURAHASHI Shun-Ichi
Department of Chemistry, Faculty of Engineering Science, Osaka University
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Tsumiyama Tatsuo
Department of Chemistry, Faculty of Engineering Science, Osaka University
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