Recent Advances in Oxypalladation of Alkenes
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概要
- 論文の詳細を見る
<I>Intramolecular cyclizations involving oxypalladation as a key step provide useful entries to oxygen-atom containing heterocycles. The oxypalladation process is highly indispensable rout to synthesizing acetals or ketones. Surveyed in this article is recent progress relevant to these oxidations from both synthetic and mechanistic viewpoints, and particular attention will be paid to the role of molecular oxygen and copper salts in palladium catalysis.</I>
- 社団法人 有機合成化学協会の論文
- 1995-11-01
著者
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MURAHASHI Shun-ichi
Department of Chemistry, Graduate School of Engineering Science, Osaka University
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Hosokawa Takahiro
Department Of Biology Faculty Of Science Kobe University
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Hosokawa Takahiro
Department Of Chemistry Faculty Of Engineering Science Osaka University
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Murahashi Shun-ichi
Department Of Applied Chemistry Okayama University Of Science
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Murahashi Shun-ichi
Department Of Chemistry Faculty Of Engineering Science Osaka University
関連論文
- Oxidation of Ethanol Induced by Simple Polyphenols : Prooxidant Property of Polyphenols
- Asymmetric Synthesis of β-Amino Acids by Addition of Chiral Enolates to Nitrones via N-Acyloxyiminium ions
- Reversal of Diastereoselectivity of the Reaction of Chiral Boron and Titanium Enolates with Nitrones via N-Acyloxyiminium Intermediates.Asymmetric Synthesis of Diastereomeric α-Substituted β-Amino Acids
- Ruthenium-Catalyzed Oxidation of Cyclic Acetals with tert-butyl Hydroperoxide. A Facile Synthesis of Glycol Monoesters
- Regioselective Synthesis of Nitrones by Decarboxylative Oxidation of N-Alkyl-α-amino Acids and Application to the Synthesis of 1-Azabicyclic Alkaloids
- Palladium-Catalyzed Double and Single Carbonylations of β-Amino Alcohols. Selective Synthesis of Morpholine-2,3-diones and Oxazolidin-2-ones and Applications for Synthesis of α-Oxo Carboxylic Acids
- Palladium-Catalyzed Asymmetric Alkylation of 2,3-Alkadienyl Phosphates. Synthesis of Optically Active 2-(2,3-Alkadienyl)malonates
- Mating aggregation and copulatory success by males of the stink bug, Megacopta punctatissima (Heteroptera: Plataspidae)
- Reversal of Regioselectivity in Wacker-Type Oxidation of Simple Terminal Alkenes and Its Paired Interacting Orbitals (PIO) Analysis
- Recent Advances in Oxypalladation of Alkenes
- Osmium-Catalyzed Oxidative Transformation of Alkenes to α-Ketols with Peracetic Acid
- A New Way for Efficient Catalysis by Using Low Valent Ruthenium Complexes as Redox Lewis Acid and Base Catalysts
- Organic Synthesis and Catalysis
- Glycine-Selective Ruthenium Catalyzed Oxidative Modification of Short Peptides
- Alkylation of ketoxime with dichloromethane using bases under phase-transfer conditions. Formation of methylene dioxime and novel heteromacrocyclic compounds.
- Palladium-catalyzed reaction of 2-vinyl-2,3-dihydrobenzofurans and chroman with nucleophiles.
- Reactivity of exo- and endo-Tricyclo[3.2.1.02,4]octan-8-ylidenes and 7-Norbornenylidene
- Synthesis of phenethylamines by hydrogenation of .BETA.-nitrostyrenes.
- Asymmetric addition of organometallic reagents to homochiral .BETA.-ketoacetals.
- cis-Oxypalladation complexes derived from (1R,5R)-2(10),3-pinadiene and their utilization in Pd(II)-catalyzed enantioselective cyclization of 2-(trans-2-butenyl)phenols.
- Catalysis of Pd(II)-catalyzed acetalization of alkenes with diols.
- Palladium-promoted transformation of .BETA.-amino ketones to enaminones.