Preparation of poly(p-phenylene) by electrooxidative polymerization in acidic media.
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概要
- 論文の詳細を見る
The electro-oxidative polymerization of benzene in the presence of strong acids yields poly(<I>p</I>-phenylene) efficiently. A strong protonic acid such as trifluoromethanesulfonic acid or Lewis acid such as an aluminum trichloride forms a complex with benzene and reduces the oxidation potential of benzene to 1.7 V, which brings about the high current efficiency. The acids act both as an electrolyte and as a catalyst in this polymerization of benzene.
- 公益社団法人 日本化学会の論文
著者
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ASADA Toshio
Department of Polymer Chemistry, Waseda University
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Asada Toshio
Department Of General Education College Of Engineering Shizuoka University
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Nishide Hiroyuki
Department Of Applied Chemistry Waseda University
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Yamamoto Kimihisa
Department Of Chemistry Faculty Of Science & Technology Keio University
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Tsuchida Eishun
Department Of Applied Chemistry Waseda University
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Yamamoto Kimihisa
Department of Polymer Chemistry, Waseda University
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