The preparation of poly(dihydroxyphenylene) through the electro-oxidative polymerization of hydroquinone.
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概要
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Hydroquinone is electro-oxidatively polymerized to poly(dihydroxyphenylene) on the Pt electrode, whose structure was confirmed by spectroscopic measurements. The polymerization proceeds via an oxidative and cationic mechanism. The poly(dihydroxyphenylene) thus formed is a Nernstian-type electro-active polymer (<I>E</I>°=0.7 V vs. Ag/AgCl in an acidic medium) and shows a redox reaction through two-electron transfer, accompanied by proton dissociation on the Pt electrode.
- 公益社団法人 日本化学会の論文
著者
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Asada Toshio
Department Of General Education College Of Engineering Shizuoka University
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Nishide Hiroyuki
Department Of Applied Chemistry Waseda University
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Yamamoto Kimihisa
Department Of Chemistry Faculty Of Science & Technology Keio University
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Tsuchida Eishun
Department Of Applied Chemistry Waseda University
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