Thermal and photochemical reactions of 10-methyl-9-phenylacridinium chloride in alcohols.
スポンサーリンク
概要
- 論文の詳細を見る
The photoreduction of 10-methyl-9-phenylacridinium chloride in methanol containing K<SUB>2</SUB>CO<SUB>3</SUB> involves the nucleophilic addition of methanol to the 9-position of the acridinium cation, the photoinduced heterolysis of the methanol adduct, and the hydride transfer from the alkoxide anion to the acridinium cation in the nonrelaxed ground states to give 9,10-dihydro-10-methyl-9-phenylacridine.
- 公益社団法人 日本化学会の論文
著者
-
Kano Koji
Department Of Molecular Science And Technology Doshisha University
-
Zhou Bin
Department of Applied Chemistry, Faculty of Engineering, Doshisha University
-
Hashimoto Shizunobu
Department of Applied Chemistry, Doshisha University
関連論文
- Effects of Anions in Subphases on a Langmuir Monolayer of N,N-Dimethyl-1-octadecanamine
- Recognition of Helicity by Native Cyclodextrins.Highly Enantioselective Complexation of Tetrahelicene Dicarboxylic Acid with β-Cyclodextrin
- Chiral Recognition of Tetrahelicene Dicarboxylic Acid by Linear Dextrins
- Tetraarylporphyrins as Probes for Studying Mechanism of Inclusion-complex Formation of Cyclodextrins. Effect of Microscopic Environment on Inclusion of Ionic Guests
- Recognition of Planar Chirality by Cyclodextrins
- Mechanism for Aerobic Oxidation of 3, 5-Di-tert-butylcatechol to 3, 5-Di-tert-butyl-o-benzoquinone Catalyzed by Di-μ-hydroxo-dicopper(II) Complexes of Peralkylated Ethylelnediamine Ligands
- Efficient Oxidation of Various Phenols Catalyzed by Di-μ-hydroxodicopper(II) Complexes of a Hexapyrdine Dinucleating Ligand
- A Superoxodicopper(II)Complex Oxidatively Generated by a Reaction of Di-μ-hydroxodicopper(II)Complex with Hydrogen Peroxide
- Reexamination of Cyclodextrin-Induced Conformational Enantiomerism of Bilirubin in Aqueous Solution
- Rb1 Protects Endothelial Cells from Hydrogen Peroxide-Induced Cell Senescence by Modulating Redox Status
- Chiral Recognition of Ru(phen)^_3 by Anionic Cyclodextrins
- Heptakis(2, 3-di-O-carboxymethyl)-β-cyclodextrin as a pH-sensitive Host
- Polar Effect on the Stacking Interaction between a Zinc Complex of an Anionic Porphyrin and Anionic Aromatics
- Entropy-Dominating Strong Binding of Carboxylate Anions to Protonated Aminocyclodextrin
- Peroxodiiron Complexes of Polypyridine Ligands : Syntheses, Physicochemical Properties, and Thermal Stability Markedly Enhanced by Hexapyridine Dinucleating Ligand
- LASER TWO-PHOTON IONIZATION TECHNIQUE FOR A HIGH SENSITIVE DETECTION OF PYRENE
- Reversible O_2-Binding and Activation with Dicopper and Diiron Complexes Stabilized by Various Hexapyridine Ligands. Stability, Modulation, and Flexibility of the Dinuclear Structure as Key Aspects for the Dimetal/O_2 Chemistry
- Photochemistry in Micellar System. II. Photochemical Reduction of β-Arylquinonesulfonates in the Presence of Cationic Surfactants.
- Photochemistry in Micellar System. I. Stabilization of the Radical Anions of Anthraquinonesulfonates
- Photoinduced one-electron reduction of 1-benzyl-3-carbamoylpyridinium chloride and 3,5-bis(ethoxycarbonyl)-2,6-dimethylpyridine.
- Self aggregation of cationic porphyrin in water.
- A novel synthesis of phenyl carboxylates.
- Exciplexes in perfluorohydrocarbon. Charge-transfer interaction between exciplexes and perfluorohexane.
- Thermal and photochemical reactions of 10-methyl-9-phenylacridinium chloride in alcohols.
- Photochemical Reduction of Nitrobenzene and Its Reduction Intermediates. IX. The Photochemical Reduction of 4-Nitropyridine in a Hydrochloric Acid-Isopropyl Alcohol Solution
- Fluorescence quenching of perfluoronaphthalene by triethylamine.
- Kinetic study of the reactions of phenacyl benzoates with trialkyl phosphites.
- Elongation of Circulation Time of a Diatomic Molecule Receptor in Bloodstream by Attachment to Small Gold Nanoparticles
- Strong van der Waals interactions in water. Molecular complexes of porphyrins and quinones in organic and aqueous media.