Reaction of rifamycin S with hexahydro-1,3,5-triazines prepared from formaldehyde and primary aliphatic amines.

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概要

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• Rifamycin S (<B>1</B>) and 25-<I>O</I>-deacetylrifamycin S reacted with 1,3,5-tri-<I>t</I>-butylhexahydro-1,3,5-triazine to give deep-blue compounds. The structures of the deep-blue compounds are discussed based on <SUP>13</SUP>C NMR data, and it is concluded that the earlier structures should be partly re-revised. The mechanism of formation of the deep-blue compounds and the reaction of <B>1</B> with several hexahydro-1,3,5-triazines, which were prepared from formaldehyde and primary aliphatic amines, are also described.

• 公益社団法人 日本化学会の論文

著者

• Tsukamoto Goro

  Pharmaceuticals Research Center Kanebo Ltd.

• Taguchi Masahiro

  Pharmaceuticals Research Center, Kanebo, Ltd.

• Aikawa Norio

  Pharmaceuticals Research Center, Kanebo, Ltd.

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• Reaction of rifamycin S with hexahydro-1,3,5-triazines prepared from formaldehyde and primary aliphatic amines.

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