Catalytic hydrogenation and cracking of anthracene over MoCl3-LiCl-KCl and NiCl2-LiCl-KCl salts.

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概要

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• The MoCl<SUB>3</SUB>– and NiCl<SUB>2</SUB>–LiCl–KCl salts, which are effective coal liquefaction catalysts, promoted the hydrogenation of anthracene (at 400 °C for 1 h with 9.8 MPa H<SUB>2</SUB>) and afforded tetrahydro- and octahydro- as well as dihydroanthracene as major products. However, these catalysts did not remarkably enhance the ring-opening cracking reactions. A comparative examination suggested that the addition of LiCl–KCl to MoCl<SUB>3</SUB> and NiCl<SUB>2</SUB> suppressed their cracking ability and improved their hydrogenation selectivity.

• 公益社団法人 日本化学会の論文

著者

• Song Chunshan

  Department Of Materials Science And Engineering Fuel Science Program Pennsylvania State University

• Nomura Masakatsu

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Ono Tomohiro

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Song Chunshan

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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