The hydrocracking of a heavy anthracene oil over molten salt catalysts.

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概要

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• The hydrocracking of a heavy anthracene oil over molten salt catalysts (zinc chloride or a binary mixture of zinc chloride and another metal chloride) at 400 °C for 3 h in a batch autoclave system was carried out, and the products were mainly identified by means of GC-MS. The effects of the hydrogen pressure (60 or 100 kg/cm<SUP>2</SUP>), the quantity of the catalyst, and the addition of metal chloride (potassium chloride or copper(I) chloride) to zinc chloride on the product distribution were examined and discussed. Based on the detailed product analysis, it was found that <I>cata</I>-condensed polycyclic aromatic compounds were hydrocracked more efficiently than <I>peri</I>-condensed polycyclic aromatic compounds. The CuCl/ZnCl<SUB>2</SUB> molten salt displayed an excellent catalytic activity for the hydrocracking of the heavy anthracene oil.

• 公益社団法人 日本化学会の論文

著者

• NOMURA Masakatsu

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Nakatsuji Yohji

  Department Of Applied Chemistry Faculty Of Engineering Osaka Institute Of Technology

• Nomura Masakatsu

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Kikkawa Shoichi

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Fujioka Shigeyuki

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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