The hydrocracking of solvent refined coals over molten salt catalysts.

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概要

• 論文の詳細を見る

• The hydrocracking of Y\barubari SRC and Tempoku SRC over ZnCl<SUB>2</SUB>/CuCl or ZnCl<SUB>2</SUB> molten salt was examined at 350 or 400 °C for 3 h in a batch autoclave system. The reactivity of SRC under the hydrocracking conditions with the molten salts was estimated mainly by comparison with the results obtained in the study using a variety of polynuclear aromatic hydrocarbons. The presence of hetero atoms (especially, the hydroxyl group) in SRC may be supposed to play an important role in this hydrocracking using molten salts. In addition, the average structures of SRC, according to the GAMSG method, are offered, and the usefulness is examined from the point of view of the reactivity of SRC in the presence of molten salts.

• 公益社団法人 日本化学会の論文

著者

• Nakatsuji Yohji

  Department Of Applied Chemistry Faculty Of Engineering Osaka Institute Of Technology

• Nomura Masakatsu

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Kikkawa Shoichi

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Ikkaku Yasuhiko

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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