ESR spectra of radical ions generated from 5,10-dihydroindeno(2,1-a)indene.
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概要
- 論文の詳細を見る
While each the ESR hyperfine coupling constants (hfc's) for the aromatic protons of the anion radical derived from 5,10-dihydroindeno[2,1-<I>a</I>]indene (<B>2</B><SUP>−·</SUP>) is similar to that of the corresponding protons of the cation radical of the same compound (<B>2</B><SUP>+·</SUP>) as well as of the radical ions of (<I>E</I>)-stilbene (<B>1</B><SUP>−·</SUP> and <B>1</B><SUP>+·</SUP>), the methylene protons of <B>2</B><SUP>−·</SUP> shows an unusually large hfc value, which is much larger than that of <B>2</B><SUP>+·</SUP>. This is interpreted in terms of the so-called "Whiffen Effect."
- 公益社団法人 日本化学会の論文
著者
-
Higuchi Jiro
Department Of Applied Chemistry Faculty Of Engineering Yokohama National University
-
Suzuki Hiroshi
Department Of Allergy And Immunology National Research Institute For Child Health & Development
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Ogawa Keiichiro
Department Of Chemistry Graduate School Of Arts And Sciences The University Of Tokyo
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Tajima Kunihiko
Department Of Applied Biology Kyoto Institute Of Technology
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Ishizu Kazuhiko
Department Of Chemistry Faculty Of Science Ehime University
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