Radiation-induced polymerization of isobutyl vinyl ether by diphenyliodonium hexafluorophosphate. Contribution of free radicals to cationic polymerization.
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概要
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The radiation-induced cationic polymerization of isobutyl vinyl ether by Ph<SUB>2</SUB>IPF<SUB>6</SUB> was investigated in dichloromethane solution. The polymerization occurs in the aerated solution containing the salt and is extremely accelerated when the solution is degassed. Contribution of radiolytically produced radicals to the cationic initiation is described. Results for the polymerization by Ph<SUB>3</SUB>SPF<SUB>6</SUB> are also presented for the sake of comparison.
- 公益社団法人 日本化学会の論文
著者
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Yamamoto Yukio
The Institute Of Scientific And Industrial Research Osaka University
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Hayashi Koichiro
The Institute of Scientific and Industrial Research, Osaka University
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Teramoto Mitsuhito
The Institute of Scientific and Industrial Research, Osaka University
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