Reactions of Aziridines with Acetyl Chloride and Related Compounds
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概要
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When aziridines (<B>1</B>) were treated with acetyl compounds, such as acetyl chloride, acetic acid, acetic anhydride, and thioacetic acid, the corresponding acetamide derivatives were obtained in good yields. In the case of acetyl chloride, some derivatives of <I>N</I>-(2-chloroethyl)acetamide (<B>5</B>) were found to be unstable in the face of moisture; they were easily hydrolyzed to give <I>N</I>-(2-hydroxyethyl) acetamide hydrochlorides (<B>3</B>). The NMR spectrum of <I>N</I>-(2-mercaptoethyl)-<I>N</I>-benzylacetamide (<B>12</B>) was discussed.
- 公益社団法人 日本化学会の論文
著者
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Sudo Rokuro
Laboratory of Organic Chemistry Tokyo Institute of Technology
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Takahama Toshio
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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Sudo Rokuro
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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Okada Itaru
Laboratory of Organic Chemistry, Tokyo Institute of Technology
関連論文
- Reactions of Aziridines with Acetyl Chloride and Related Compounds
- A New Synthesis of Aziridines from β-Amino Alcohols with Triphenylphosphine Dibromide
- The Preparation of α-Amino-α-benzylmercaptopropionic Acid Derivatives