Studies on Pyrophosphates. I. A Selective Degradation of Pyrophosphates by Means of 2,6-Dichloroquinone <I>N</I>-Chloroimide
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概要
- 論文の詳細を見る
Reaction of P<SUP>1</SUP>,P<SUP>2</SUP>-dialkyl pyrophosphate with alcohols or water in the presence of 2,6-dichloroquinone <I>N</I>-chloroimide (CQC) was studied. It was found that alkyl <I>p</I>-nitrophenyl phosphates are obtained in high yields by treating P<SUP>1</SUP>,P<SUP>2</SUP>-di-<I>p</I>-nitrophenyl pyrophosphate with alcohols in the presence of CQC. Similarly, alkyl phosphates are selectively produced by the reaction of P<SUP>1</SUP>,P<SUP>2</SUP>-dialkyl pyrophosphates with water in the presence of CQC. These reactions afford a new procedure for the selective degradation of P<SUP>1</SUP>,P<SUP>2</SUP>-dialkyl pyrophosphates, especially nucleoside pyrophosphates.
- 公益社団法人 日本化学会の論文
著者
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Hata Tsujiaki
Department of Chemistry Tokyo Institute of Technology
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Chong Kyu-Jang
Department of Chemistry, Tokyo Institute of Technology
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Pong Sheng-Shung
Department of Chemistry, Tokyo Institute of Technology
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