The Copolymerization of 2-Chloroacrylaldehyde with Styrene
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概要
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The copolymerization of α-chloroacrolein (M<SUB>1</SUB>) with styrene (M<SUB>2</SUB>) has been investigated. An alternating copolymer was obtained without an initiator in dimethyl sulfoxide at 60°C. The formation of a charge-transfer complex between the respective monomers was observed by the continuous-variation method, and it was found that this complex plays an important role in the polymerization. Meanwhile, in the case of the BF<SUB>3</SUB>OEt<SUB>2</SUB>-catalyzed system, it was observed that the polymerization temperature strongly affected the copolymerizability and the structure of the copolymer.
- 公益社団法人 日本化学会の論文
著者
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MAESHIMA Toshihisa
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
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Matsubara Yoshio
Department Of Applied Chemistry Faculty Of Science And Engineering Kinki University
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YOSHIHARA Masakuni
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
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Yoshihara Masakuni
Department Of Applied Chemistry Faculty Of Science And Engineering Kinki University
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Kavi Parimal
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
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