Mixed-ligand Complexes of Copper(II). II. A Study of Dismutation Constants
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概要
- 論文の詳細を見る
The dismutation constants for mixed-ligand complexes of copper(II) involving, as bidentate ligands, ethylenediamine, L-alanine, β-alanine, and <I>N</I>,<I>N</I>-dimethylglycine were determined at two or three temperatures by both the spectrophotometric and ESR methods, and the thermodynamic constants were then derived from those data. It was found for these systems that the entropy change plays a main role in governing the equilibrium between a mixed-ligand complex and its parent complexes, and that the differences in the dismutation constants among the mixed-ligand complexes are due to the small but different values of the enthalpy term.
- 公益社団法人 日本化学会の論文
著者
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Yokoi Hiroshi
Chemical Research Institute of Non-aqueous Solutions, Tohoku University
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Isobe Taro
Chemical Research Institute of Non-Aqueous Solutions, Tohoku University
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Otagiri Masaki
Chemical Research Institute of Non-aqueous Solutions, Tohoku University
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