Infrared absorption spectrum of gaseous CF3CO radical: Recording on a rapid-scan infrared spectrometer.
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概要
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A rapid-scan infrared spectrometer capable of scanning the region from 5000 to 650 cm<SUP>−1</SUP> in 200 μs was constructed and successfully applied to study CF<SUB>3</SUB>CO radical produced by flash photolysis. Four absorption bands of the radical were detected at 1574, 1338, 1115, and 1024 cm<SUP>−1</SUP> for scanning started 25 μs after the firing of a Xe flash tube. They were tentatively assigned to the CO stretching, CF<SUB>3</SUB> stretching (a species), CF<SUB>3</SUB> stretching (e species), and CC stretching vibrations, respectively.
- 公益社団法人 日本化学会の論文
著者
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KOZUKA Muneteru
Chemical Research Institute of Non-Aqueous Solutions
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Isobe Taro
Chemical Research Institute of Non-Aqueous Solutions, Tohoku University
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Kozuka Muneteru
Chemical Research Institute of Non-Aqueous Solutions, Tohoku University
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Kozuka Muneteru
Chemical Research Institute of Non-Aqueous Solution, Tohoku University
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