The Fluorination of Carbonyl Sulfide

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概要

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• The electrochemical fluorination of carbonyl sulfide has been carried out. Garbonyl fluoride and sulfur hexafluoride were obtained as the principal products. The influence of the operating conditions on the reaction has been examined. In addition, a method has been developed for the production of sulfur hexafluoride. This involves the passage of carbon monoxide and sulfur over a catalyst; the resultant gas formed is subsequently introduced into a current-carrying anhydrous hydrogen fluoride in an electrolytic cell. Sulfur hexafluoride was thus obtained in a good yield.

• 公益社団法人 日本化学会の論文

著者

• Nagase Shunji

  Government Industrial Research Institute

• Baba Hajime

  Government Industrial Research Institute

• Nagase Shunji

  Government Industrial Research Institute, Nagoya

• Abe Takashi

  Government Industrial Research Institute, Nagoya

• Kodaira Kazuo

  Government Industrial Research Institute, Nagoya

• Kodaira Kazuo

  Government Industrial Research Institute

• Abe Takashi

  Government Industrial Research Institute

関連論文

• Electrochemical Fluorination of 2,2,3,3-Tetrafluoro-1-propanol
• Electrochemical Fluorination of Aldehydes
• The electrochemical fluorination of trifluoromethyl-substituted benzenes.
• Electrochemical fluorination of ethanethiol.
• The Electrochemical Fluorination of Dithiols and Cyclic Sulfides
• The electrochemical fluorination of aliphatic primary monohydric alcohols and aldehydes.
• The Fluorination of Carbon Monoxide, Carbonyl Chloride, and Carbonyl Fluoride
• The Fluorination of Carbonyl Sulfide
• Electrochemical fluorination of thiols.
• Chlorofluorination of Carbon Disulfide and Sulfur
• The Electrochemical Fluorination of s-Triazines
• The Electrochemical Fluorination of Benzenes and Pyridines
• Preparation of fluorine-containing phenylacetylenes by the method of introduction of the ethynyl group using 1,1-dichloro-2,2-difluoroethene.

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