Electrochemical Fluorination of Aldehydes

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概要

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• Aldehydes were fluorinated electrochemically to prepare prefluorocarboxylic acids. The results were compared with those obtained from the fluorination of alcohols, esters, ketones and unsaturated compounds.<BR>Generally, the yield of perfluorocarboxylic acids was considerably lower in aldehydes because of a great fragmentation or polymerization in the fluorination reaction. No evidence could be obtained for the formation of a detectable amount of partially fluorinated aldehydes or perfluoroaldehydes in the reaction. The mechanism for the formation of perfluorocarboxylic acid fluorides from aldehydes was discussed.

• 社団法人 日本化学会の論文

著者

• Nagase Shunji

  Government Industrial Research Institute

• Baba Hajime

  Government Industrial Research Institute

• Kojima Rimpei

  Government Industrial Research Institute

• Nagase S.

  Government Industrial Research Institute

関連論文

• Electrochemical Fluorination of 2,2,3,3-Tetrafluoro-1-propanol
• Electrochemical Fluorination of Aldehydes
• The electrochemical fluorination of trifluoromethyl-substituted benzenes.
• Electrochemical fluorination of ethanethiol.
• The Electrochemical Fluorination of Dithiols and Cyclic Sulfides
• The electrochemical fluorination of aliphatic primary monohydric alcohols and aldehydes.
• The Fluorination of Carbon Monoxide, Carbonyl Chloride, and Carbonyl Fluoride
• The Fluorination of Carbonyl Sulfide
• Electrochemical fluorination of thiols.
• Chlorofluorination of Carbon Disulfide and Sulfur
• The Electrochemical Fluorination of s-Triazines
• The Electrochemical Fluorination of Benzenes and Pyridines

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