The electrochemical fluorination of trifluoromethyl-substituted benzenes.

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概要

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• The electrochemical fluorination of benzenes containing one or two trifluoromethyl groups has been carried out. They afforded perfluorocyclohexane derivatives with the trifluoromethyl group in good yields. Chlorobenzenes containing a trifluoromethyl group yielded chlorinecontaining perfluorocyclohexane derivatives carrying the trifluoromethyl group. Trifluoromethylbenzonitriles gave perfluoro(dimethylcyclohexane)s, whereupon the nitrile group was converted into a trifluoromethyl group, thus releasing nitrogen trifluoride. The electrochemical fluorination of a trifluoromethylnaphthalene gave perfluoro(methyldecahydronaphthalene) only in a small yield.

• 公益社団法人 日本化学会の論文

著者

• Nagase Shunji

  Government Industrial Research Institute

• Baba Hajime

  Government Industrial Research Institute

• Abe Takashi

  Government Industrial Research Institute, Nagoya

• Kodaira Kazuo

  Government Industrial Research Institute, Nagoya

• Yonekura Michimasa

  Government Industrial Research Institute

• Kodaira Kazuo

  Government Industrial Research Institute

• Abe Takashi

  Government Industrial Research Institute

関連論文

• Electrochemical Fluorination of 2,2,3,3-Tetrafluoro-1-propanol
• Electrochemical Fluorination of Aldehydes
• The electrochemical fluorination of trifluoromethyl-substituted benzenes.
• Electrochemical fluorination of ethanethiol.
• The Electrochemical Fluorination of Dithiols and Cyclic Sulfides
• The electrochemical fluorination of aliphatic primary monohydric alcohols and aldehydes.
• The Fluorination of Carbon Monoxide, Carbonyl Chloride, and Carbonyl Fluoride
• The Fluorination of Carbonyl Sulfide
• Electrochemical fluorination of thiols.
• Chlorofluorination of Carbon Disulfide and Sulfur
• The Electrochemical Fluorination of s-Triazines
• The Electrochemical Fluorination of Benzenes and Pyridines
• Preparation of fluorine-containing phenylacetylenes by the method of introduction of the ethynyl group using 1,1-dichloro-2,2-difluoroethene.

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