Charge-transfer and Proton-transfer in the Formation of Molecular Complexes. VII. Complex Isomerism in Several Anilinium Alkyl-substitiited Picrates
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概要
- 論文の詳細を見る
<I>o</I>-Chloroanilinium and <I>o</I>-bromoanilinium methylpicrates are obtainable not only as yellow-colored salts, but also as unstable, monotropic reddish-orange forms. Spectroscopic studies have revealed that the latter are charge-transfer complexes composed of the aniline molecule acting as an electron-donor and the acid molecule acting as an acceptor. Similar monotropic forms have been found in combinations of dimethylpicric acid with <I>o</I>-iodo-aniline, <I>o</I>-bromoaniline, and <I>N</I>,<I>N</I>-dimethylamino-<I>p</I>-benzaldehyde.
- 公益社団法人 日本化学会の論文
著者
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Inoue Nobuaki
Department Of Agro-bioscience Faculty Of Agriculture Iwate University
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Matsunaga Yoshio
Department of Chemistry, Faculty of Science, Hokkaido University
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Inoue Nobuaki
Department of Chemistry, Faculty of Science, Hokkaido University
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