A New Reagent for the Syntheses of <I>N</I>-Monoalkylated Hydroxylamines; <I>N</I>-Tosyl-<I>O</I>-2,4,6-trimethylbenzylhydroxylamine

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概要

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• The reactions of <I>N</I>-tosyl-<I>O</I>-2,4,6-trimethylbenzylhydroxylamine with primary alkyl halides yielded the protected hydroxylamines. The simultaneous cleavage of <I>N</I>-tosyl- and <I>O</I>-2,4,6-trimethylbenzyl groups with hydrogen bromide in acetic acid gave the corresponding <I>N</I>-monoalkylated hydroxylamines such as <I>N</I>-benzylhydroxylamine, 1-amino-3-hydroxyaminopropane and DL-3-hydroxyamino-2-aminopropionic acid.

• 公益社団法人 日本化学会の論文

著者

• Kurita Hideaki

  Sagami Chemical Research Center

関連論文

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• A New Reagent for the Syntheses of N-Monoalkylated Hydroxylamines; N-Tosyl-O-2,4,6-trimethylbenzylhydroxylamine

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