The Preparation of Several Copper(I) and Silver Polyfluoroalkanethiolates and of Polyfluoroalkyl Aryl (or Alkyl) Sulfides
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概要
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2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane (<B>1</B>) in the KF-DMF system was treated with hexafluoropropene in the presence of CuBr to give copper(I) 1,1,2-tris(trifluoromethyl)tetrafluoropropanethiolate (<B>4</B>). A similar reaction of <B>1</B> with alcohols in the presence of CuBr or AgNO<SUB>3</SUB> gave copper(I) (<B>6</B>) and silver 1-alkoxy-1-trifluoromethyl-2,2,2-trifluoroethanethiolate (<B>7</B>) respectively. These copper(I) and silver polyfluoroalkanethiolates condensed with aryl or alkyl iodides to afford 1,1,2-tris(trifluoromethyl)-tetrafluoropropyl (<B>8</B>) and 1-alkoxy-1-trifluoromethyl-2,2,2-trifluoroethyl aryl(or alkyl) sulfides (<B>9</B>).
- 公益社団法人 日本化学会の論文
著者
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Kitazume Tomoya
Department Of Bioengineering Tokyo Institute Of Technology
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Ishikawa Nobuo
Department of Chemical Engineering, Tokyo Institute of Technology
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