Adsorption of Aniline Derivatives on Platinum Electrode in Aqueous Alkaline Solution
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In the adsorption of aniline derivatives on Pt electrode, a linear relation was observed between the chemical shift of the <I>m</I>- and <I>p</I>-amino protons and the inhibiting effect on the anodic oxidation of methanol. However, <I>o</I>-alkylanilines and chloroanilines showed deviations due to steric hindrance and strong interactions, respectively.
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