The Determination of Formation Constants by Measurements of Molar-volume Changes

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概要

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• Density measurements were made with a solution containing equivalent amounts of diethylenetriamine and the copper(II) ion, and with solutions of different concentrations of potassium hydroxide. The measurements were also made with systems in which the above-mentioned solutions were mixed. The molar-volume changes due to the complex formation were calculated from the density. The results were used for the calculation of the formation constant of the monohydroxo-diethylenetriamine-copper(II) ion.

• 公益社団法人 日本化学会の論文

著者

• Takamoto Susumu

  Department of Chemistry, Faculty of Science, Gakushuin University

• Watanabe Norio

  Department of Chemistry, Faculty of Science, Gakushuin University

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