Acyl cyanide. IV. The reduction of phenyl-substituted carbamoyl cyanides with metal hydrides.
スポンサーリンク
概要
- 論文の詳細を見る
The reaction of phenylcarbamoyl cyanide with LiAlH<SUB>4</SUB> or NaBH<SUB>4</SUB> gave glycine anilide, <I>N</I>-phenylethylenediamine, and <I>N</I>-methylaniline. With the latter hydride, 4-amino-1,3-diphenyl-2-imidazolidinone was also formed. The reduction of diphenylcarbamoyl cyanide with LiAlH<SUB>4</SUB> gave <I>N</I>-methyldiphenylamine as the only reduction product.
- 公益社団法人 日本化学会の論文
著者
-
Oku Akira
Department Of Chemistry And Materials Technology Kyoto Institute Of Technology
-
Ueda Hiroyuki
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
-
Mashio Fujio
Department of Chemistry, Kyoto Institute of Technology
-
Inoue Jiro
Department of Chemistry, Kyoto Institute of Technology
関連論文
- Bacterial Communities Constructed in Artificial Consortia of Bacteria and Chlorella vulgaris
- BCD-07 TRNSMISSION ERROR IN SYNCHRONOUS BELT DRIVES UNDER DYNAMIC CONDITIONS(BELT AND CHAIN DRIVES)
- Adnexal Masses Caused by Pelvic Inflammatory Disease : MR Appearance
- Paraneoplastic syndromes associated with ovarian neoplasms
- Asymmetric Synthesis of Functionalized Secondary Alcohols by Catalytic Ring-Cleavage Reactions of Cyclic Acetals Derived from (R)-1, 3-Butanediol
- Donor-Acceptor Binary Photocatalysis System Illustrated by the Intramolecular Cyclization of a Cyclopropanone Acetal Tethered to Cyclohexen-2-one
- Thermoluminescence studies of ordinary chondrites in the Japanese Antarctic meteorite collection, IV: Asuka ordinary chondrites
- BCD-20 INFLUENCE OF IDLER ON TRANSMISSION ERROR IN SYNCHRONOUS BELT DRIVES : UNDER TRANSMISSION FORCE(BELT AND CHAIN DRIVES)
- Deprotection of Acetals and Silyl Ethers by DDQ. Is DDQ a Neutral Catalyst?
- Glow Discharge in DC Magnetic Field; Effect of the Applied Microwave on the Detection Sensitivity to Optical-Wave Signal
- Injection Locking Effect of Optical Detection by Glow Discharge in DC Magnetic Field
- The Gas Filled Osaka Tube Oscillator
- Several Characteristics of the Hot Cathode Discharge Osaka Tube
- Cyclopropylidene Dianion Equivalent. Preparation of 1,1-Dilithio-2,2-diphenylcyclopropane
- Design of a Novel Cyclopropane Donor Bis (trimethylsilylmethyl) cyclopropane and Its Electron Transfer Reactions
- The Peracid-oxidation of Tetraphenylallene: The Formation of Hydroxyindanone and Its Oxidative Transformation
- Acyl cyanide. III. Thermal and base-catalyzed reactions of phenylcarbamoyl cyanide.
- Substituent effects in the Diels-Alder reaction of substituted benzynes with hexamethylcyclohexa-2,4-dienone.
- Acyl cyanide. VI. The synthesis of 1-cyano-1-alkenyl esters by the reaction of acyl cyanides with acid chlorides. Synthesis and mechanism.
- Regio- and stereoselectivity of the intramolecular C-H insertion by cyclopropylidenes bearing a remote oxido substituent.
- A formylcarbonium ion synthon. Synthesis of 3-thio-substituted 2-amino acids and thio-substituted enamines from 2-acyloxyacrylonitriles.
- The synthesis of 1,2,3,4-tetramethyl-5-nitronaphthalene and 1,2,3,4-tetramethyl-6-nitronaphthalene.
- Acyl cyanide. IV. The reduction of phenyl-substituted carbamoyl cyanides with metal hydrides.
- Acyl cyanide. V. The synthesis of 1-cyano-1-alkenyl esters by the reaction of acyl cyanides with acid anhydrides and isocyanates.
- Intramolecular [2+2] photocycloaddition. 5. Synthetic methods toward [2.n]-, [3.n]-, and [4.n]naphthalenophane skeletons by using .ALPHA.,.OMEGA.-bis(vinylnaphthyl)alkanes.