Activation of carbon dioxide by tetraphenylporphinatoaluminium methoxide. Reaction with epoxide.
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概要
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α,β,γ,δ-Tetraphenylporphinatoaluminium methoxide reacts reversibly with carbon dioxide in the presence of 1-methylimidazole, and this carbon dioxide is activated to react with propylene oxide to produce propylene carbonate under atmospheric pressure and at room temperature.
- 公益社団法人 日本化学会の論文
著者
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Inoue Shohei
Department Of Dermatology Miyazaki Medical College
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Takeda Norikazu
Department of Respiratory Medicine, Showa University Fujigaoka Hospital, Japan
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Takeda Norikazu
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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