Reactivity of (porphinato)aluminum phenoxide and alkoxide as active initiators for polymerization of epoxide and lactone.
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概要
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Reactivity of the axial aluminum-phenoxyl and -alkoxyl bond (Al-X) of aluminum porphyrin (<B>1</B>, (TPP)AIX, (TPP): (5,10,15,20-tetraphenylporphinato)) toward epoxide, β-lactone, and ε-lactone was examined in relation to the ring-opening polymerization of these cyclic compounds catalyzed by <B>1</B>. The reactivity of<BR>(<U>Remark: Graphics omitted.</U>)<BR>aluminum phenoxide was in the order, epoxide>β-lactone>ε-lactone, while that of the alkoxide, ε-lactone>β-lactone.
- 公益社団法人 日本化学会の論文
著者
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Aida Takuzo
Department Of Chemistry And Biotechnology Faculty Of Engineering The University Of Tokyo
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Inoue Shohei
Department Of Dermatology Miyazaki Medical College
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Aida Takuzo
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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Yasuda Tomokazu
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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Inoue Shohei
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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