Electronic state of ethoxycarbonylnitrene generated by .ALPHA.-elimination under two-phase conditions.
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概要
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The base decomposition of ethyl <I>p</I>-nitrophenylsulfonyloxycarbamate in organic-aqueous two-phase systems in the presence of <I>cis</I>- or <I>trans</I>-4-methyl-2-pentene and quaternary ammonium or phosphonium halides afforded both stereospecific and nonstereospecific addition products of ethoxycarbonylnitrene. The electronic state of the nitrene was analyzed on the basis of Skell's hypothesis.
- 公益社団法人 日本化学会の論文
著者
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SENO Manabu
Institute of Industrial Science, The University of Tokyo
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Kise Hideo
Institute of Industrial Science, The University of Tokyo
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Namba Tomiyuki
Institute of Industrial Science, The University of Tokyo
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