Kinetic parameters of thermal dehydration and decomposition of Zeise's salt hydrates.
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概要
- 論文の詳細を見る
The kinetic parameters of the dehydration of Zeise's salt hydrates, K[PtCl<SUB>3</SUB> (olefin)]·H<SUB>2</SUB>O, (olefin; CH<SUB>2</SUB>=CH<SUB>2</SUB>, CH<SUB>3</SUB>CH=CH<SUB>2</SUB>, C<SUB>2</SUB>H<SUB>5</SUB>CH=CH<SUB>2</SUB>, <I>n</I>-C<SUB>3</SUB>H<SUB>7</SUB>CH=CH<SUB>2</SUB> and <I>n</I>-C<SUB>4</SUB>H<SUB>9</SUB>CH=CH<SUB>2</SUB>) and the thermal decomposition of Zeise's dimers were determined by using DTA and TG. By comparing the kinetic parameters with the data of IR and the enthalpy change of dehydration, it was shown that the important factor in determining the kinetic behavior of the dehydration is an extent of deformation of lattice at the transition state. Similarly, it was suggested that the bulkiness of ligand olefin is an important factor in governing the kinetics of the thermal decomposition reactions.
- 公益社団法人 日本化学会の論文
著者
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SENO Manabu
Institute of Industrial Science, The University of Tokyo
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Iwamoto Kazutoshi
Institute of Industrial Science, The University of Tokyo
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Iwamoto Kazutoshi
Institute of Industrial Science, University of Tokyo
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Asahara Teruzo
Institute of Industrial Science, The University of Tokyo
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