High pressure organic chemistry. III. Diels-alder reaction of thiophene with maleic anhydride.
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概要
- 論文の詳細を見る
The Diels-Alder reaction of thiophene with maleic anhydride has been investigated under conditions of very high pressure. The Diels-Alder adduct was obtained in dicbloromethane at 100 °C and 15 kbar; above a pressure of 15 kbar the reaction was highly accelerated. From the spectral data and chemical evidence it has been suggested that the adduct has the <I>exo</I>-configuration. The reactions in various solvents and with other dienophiles have also been examined.
- 公益社団法人 日本化学会の論文
著者
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OCHI Masamitsu
Faculty of Science, Kochi University
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KOTSUKI Hiyoshizo
Faculty of Science, Kochi University
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Tokoroyama Takashi
Faculty Of Science Osaka City University
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Yamasaki Nakamichi
Faculty of Science, Kochi University
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Nishizawa Hitoshi
Faculty of Science, Kochi University
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Kitagawa Sachio
Faculty of Science, Kochi University
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Matsuoka Kiyoshi
Faculty of Science, Kochi University
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Ochi Masamitsu
Faculty of Arts and Sciences, Kochi University
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