The Photochemical Reaction of Cycloöoctatetraene (C<SUB>8</SUB>H<SUB>8</SUB>)

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概要

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• By the absorption spectra, it was found that benzene and styrene were independently produced from C.O. T. when C.O.T. was excited by the light shorter than 3000 Å., and that some unknown substances giving a sharp line at 2916 Å. and two diffuse bands at 2916 Å.∼2885Å. and 2840 Å.∼2700 Å. were also produced. The gas like acetylene which can not be condensed by dry ice can be at the same time produced.<BR>The quantum yield of reaction where C. O. T. is decomposed to benzene by light near 2537 Å was about 0.1. And the light which has the shorter wave length than 2500 Å. mainly contributes to the reaction in which C. O. T. decomposes to benzene.

• 社団法人 日本化学会の論文

著者

• Shida Shoji

  Laboratory of Physical Chemistry and Inorganic Chemistry, Tokyo Institute of Technology (Tokyo Kogyo Daigaku)

• Tanaka Ikuzo

  Laboratory of Physical Chemistry and Inorganic Chemistry, Tokyo Institute of Technology (Tokyo Kogyo Daigaku)

• Miyakawa Seinosuke

  Laboratory of Physical Chemistry and Inorganic Chemistry, Tokyo Institute of Technology (Tokyo Kogyo Daigaku)

• Tanaka Ikuzo

  Laboratoire de Chimie minérale et de Chimie physique, Institut de Technologie de Tokyo (Tokyo Kôgyô-Daigaku)

関連論文

• The Photochemical Reaction of Cycloöoctatetraene (C8H8)
• Magnetic Property and Resonance Character of Cycloöctatetraene (C8H8)
• Molecular Orbital Treatment of the Ultraviolet Spectra of Cycloöctatetraene
• Études spectrochimiques du cyclooctatétraène (C8H8) et du C10H10
• The Radiolysis and Photolysis of Cycloheptatriene
• The Radiolysis of Squalane (C30H62) from －196°C to 350°C
• Very-high-dose-rate Radiolysis of n-Butane in the Gas Phase. The Effect of the Addition of Electron Scavengers
• Water Formation in the Gas Phase Radiolysis of Nitrous Oxide-Hydrocarbon Mixtures
• Mechanism of Benzene Formation in the Radiation-Induced and Photochemical Reactions of Acetylene
• The γ-Radiolysis of Liquid n-Hexane. The Effects of Radical, Electron, and Positive-ion Scavengers
• Photolysis of Acetylene at 1849 Å
• The Electron-scavenging Process in 3-Methylhexane Glass at 77 K Studied by ESR
• The Radiophoto-luminescence of γ-Irradiated Hydrocarbon Glasses at 77 K
• Chemi-ionization of Cs*(82P1⁄2) with Cs and Foreign Gases
• The Vacuum Ultraviolet Photolysis of Liquid n-Hexane in the Presence of SF6
• The Measurement of Water and Other Oxygen-containing Products in the Radiolysis of Cyclohexane Solutions of Nitrous Oxide

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