Magnetic Property and Resonance Character of Cycloöctatetraene (C<SUB>8</SUB>H<SUB>8</SUB>)

スポンサーリンク

概要

• 論文の詳細を見る

• We have obtained －53.9×10<SUP>－6</SUP> at 30° as the molecular diamagnetic susceptibility of purified cycloöctatetraene, and its temperature dependence exceeding 0.5 percent over the temperature range 30° to 80° has not been detected. The diamagnetic anisotropy of this molecule has been estimated －12.6×10<SUP>－6</SUP> per mole on some assumptions, and the resonanceenergy 2.9 kcal. per mole from the thermal data.<BR>The relationship between the small anisotropy and the weak resonance character of this molecule has been discussed and explained qualitalively on the basis of the quantum mechanical considerations. Langevin's theory and the original procedure of London's method have been found to be unsuitable for the explanation of this small anisotropy.

• 社団法人 日本化学会の論文

著者

• Shida Shoji

  Laboratory of Physical Chemistry and Inorganic Chemistry, Tokyo Institute of Technology (Tokyo Kogyo Daigaku)

• Shida Shoji

  Laboratory of Physical Chemistry, Tokyo Institute of Technology

• Fujii Saburo

  Laboratory of Physical Chemistry, Tokyo Institute of Technology

関連論文

• The Photochemical Reaction of Cycloöoctatetraene (C8H8)
• Magnetic Property and Resonance Character of Cycloöctatetraene (C8H8)
• Molecular Orbital Treatment of the Ultraviolet Spectra of Cycloöctatetraene
• The Radiolysis and Photolysis of Cycloheptatriene
• The Radiolysis of Squalane (C30H62) from －196°C to 350°C
• Very-high-dose-rate Radiolysis of n-Butane in the Gas Phase. The Effect of the Addition of Electron Scavengers
• Water Formation in the Gas Phase Radiolysis of Nitrous Oxide-Hydrocarbon Mixtures
• Mechanism of Benzene Formation in the Radiation-Induced and Photochemical Reactions of Acetylene
• The γ-Radiolysis of Liquid n-Hexane. The Effects of Radical, Electron, and Positive-ion Scavengers
• Photolysis of Acetylene at 1849 Å
• The Electron-scavenging Process in 3-Methylhexane Glass at 77 K Studied by ESR
• The Radiophoto-luminescence of γ-Irradiated Hydrocarbon Glasses at 77 K
• The Vacuum Ultraviolet Photolysis of Liquid n-Hexane in the Presence of SF6
• The Measurement of Water and Other Oxygen-containing Products in the Radiolysis of Cyclohexane Solutions of Nitrous Oxide

もっと見る 閉じる

スポンサーリンク