The Polarographic Reduction and Electronic Structures of Organic Halides
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概要
- 論文の詳細を見る
The polarographic reduction potential of haloalkanes is connected with the energy of their lowest unoccupied σ level. Moreover, the reduction products are well explained in terms of the anti-bonding nature of the carbon halogen bond of the level. The polarographic reduction potential of conjugated halides is also correlated to their lowest unoccupied σ, not π, level. It has also been suggested that, in conjugated halides, the lowest unoccupied σ level might be lower than the lowest unoccupied π level and that the π→σ<SUP>*</SUP> transition might be observed.<BR>Most of the calculations have been carried out on the KDC-I digital computer of Kyoto University.
- 社団法人 日本化学会の論文
著者
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Fukui Kenichi
Faculty Of Engineering Kyoto University
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Yonezawa Teijiro
Faculty Of Engineering Kyoto University
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Kato Hiroshi
Faculty Of Engineering Tokyo Metropolitan University
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Morokuma Keiji
Faculty of Engineering Kyoto University
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