The Reaction of Tropoids and Quinone Derivatives. III. Reaction of Several Tropolones and <I>o</I>-Benzoquinone Dibenzimide
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概要
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Reaction of tropolone and <I>o</I>-benzoquinone dibenzimide was carried out and the structure of its product was determined by deriving it to a 2-phenylbenzimidazole derivative. This revealed that the product is <I>N</I>-(tropolone-5-yl)-<I>N</I>,<I>N</I>′-dibenzoly-<I>o</I>-phennylenediamine. 3-Bromotropolone and 3, 7-dibromotropolone also underwent the same reaction to afford the corresponding bromo derivatives. For the sake of identification, 1-(4′-methoxycarbonylphenyl)-2-phenylbenzimidazole was synthesized from 2-amino-4′-methyldiphenylamine.
- 公益社団法人 日本化学会の論文
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