The Radiation-Induced Exchange Reaction of Oxygen Atoms in Carbon Dioxide
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概要
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Oxygen exchange of carbon dioxide induced by β-ray irradiation has been investigated by use of oxygen isotope O<SUP>*</SUP>. From the decrease of O<SUP>*</SUP> amount, the apparent and total values of the exchange reaction, <I>G</I><SUB>corr</SUB>(-CO<SUB>2</SUB><SUP>*</SUP>) and <I>G</I><SUB>total</SUB><SUP>exc</SUP>, have been calculated to be 1.7<SUB>2</SUB> and 51, respectively. The latter value 51 would be equivalent to the forward reaction, but has been shown to be larger than the corresponding value (8.5) in Harteck's experiment.
- 社団法人 日本化学会の論文
著者
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HATADA Motoyoshi
Osaka Laboratory for Radiation Chemistry, Japan Atomic Energy Research Institute
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Hirota K.
Department Of Health And Physical Education College Of General Education University Of Tokyo
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Hirota Kozo
Department of Chemistry Faculty of Science Osaka University
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Terasaki Hideo
Osaka Laboratory Japanese Association for Radiation Research on Polymers
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