Organic Semiconductors with High Conductivity. III. Perylene-Iodine Complex
スポンサーリンク
概要
- 論文の詳細を見る
Concerning the solid complex of perylene-iodine system, it has been clarified that two sorts of molecular addition compounds are formed. One has the composition of Perylene· 1.5 I<SUB>2</SUB> (or 2 Perylene· 3 I<SUB>2</SUB>) and the other is Perylene· 3 I<SUB>2</SUB>. Both complexes are semiconductive with low resistivity; the resistivity at the room temperature is 9∼10 ohm.cm. and the energy gap is 0.06 eV. Concerning those values, both complexes possess almost the same values. Not only the elecrical properties and the magnetic properties, but also, both complexes possess similar crystal structures. To explain those facts, the structural units for those complexes have been proposed. These consist of the conjugation between perylene molecules and iodine molecules with the charge tranfer type of interaction.
- 公益社団法人 日本化学会の論文
著者
関連論文
- Third Harmonic Generation Measurements for Halogen-Doped One-Dimensional Nickel Complexes
- Structure and Properties of Titanium-Including Complex, Tris(tetramethyltetrathiafulvalene) Di-μ-fluoro-bis[tetrafluorotitanate-(IV)], (TMTTF)_3Ti_2F_
- Structure and Characterization of 9,10-Diethyl-9,10-diphospha-9,10-dihydroanthracene as an Electron Donor
- Hydrogen Rearrangements in CsHSeO_4 Accompanied with both the Phase Transition and Domain-Boundary-Movement
- Preparation and Reactions of 1,2-Thiaphospholes
- Organic Semiconductors with High Conductivity. III. Perylene-Iodine Complex
- Crystal and molecular structure of 3,8-di-t-butyl-5,6-diphenyl-1-thioxo-2,9-dithia-1-phosphabicyclo(4.3.0)nona-3,7-diene.
- Crystal and molecular structure of 4-t-butyl-5-cyano-2-phenyl-1-thioxo-7-thia-1-phosphabicyclo(2.2.1)hept-2-ene.
- An interpretation of the asymmetric induction observed in rhodium-bis(dibenzophosphole) complex catalyzed hydroformylation according to an X-ray molecular structure analysis of an iridium-(2R,3R)-2,3-O-isopropylidene-1,4-bis(5H-dibenzophosphol-5-yl)-2,3-b
- The crystal and molecular structure of perylene-2,5-dibromo-3,6-dichloro-p-benzoquinone complex.
- Electronic properties of one-dimensional iodine complex. Benzo(b)phenothiazine-I2.5.
- The crystal structure of the .BETA.'1 form of optically active .ALPHA.-monostearin.
- Classification of Phenothiazine Complexes by Structure and Electronic Properties.
- The crystal structure of o-phenylenediamine dihydroiodide.
- The crystal and molecular structure of an isomer of dibromoperylenes.