Investigation on Mixed Complexes. IV. The Formation of a Mixed Complex by Reaction of Tetracyanoniccolate(II) with Bis-(dithiooxalato)-niccolate(II)

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概要

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• It has been concluded, by the spectrophotometric method, that 1) potassium bis-(dithiooxalato)-niccolate(II) and potassium tetracyanoniccolate(II) react in solution to form a mixed complex, [Ni(C<SUB>2</SUB>S<SUB>2</SUB>O<SUB>2</SUB>)(CN)<SUB>2</SUB>]<SUP>2－</SUP>, 2) in the case of palladium(II) and platinum(II), bis-(dithiooxalato)- and tetracyano- complexes do not react in solution, unlike the case of nickel (II), and 3) the dithiooxalate ion in the complex, [Pt(C<SUB>2</SUB>S<SUB>2</SUB>O<SUB>2</SUB>)<SUB>2</SUB>]<SUP>2－</SUP>, is replaced by the cyanide ion in solution, the tetracyanoplatinate(II) ion being formed, but the formation of the mixed complex, such as [Pt(C<SUB>2</SUB>S<SUB>2</SUB>O<SUB>2</SUB>)(CN)<SUB>2</SUB>]<SUP>2－</SUP>, is not certain.

• 社団法人 日本化学会の論文

著者

• Kida S.

  Department Of Neurosurgery Kanazawa University School Of Medicine

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