Investigation on Mixed Complexes. V. A Conductometric Study of Cyano-ethylenediamine Complexes

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概要

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• The conductometric method was applied to the determination of the formation of mixed complexes in solution, using the method of continuous variation. It was shown that<BR>1) [Ni en<SUB>3</SUB>]<SUP>2+</SUP> reacts with CN<SUP>－</SUP> and forms [Ni(CN)<SUB>4</SUB>]<SUP>2－</SUP> only, leading to the same conclusion as in the spectrophotometric investigation carried out previously.<BR>2) [Pt en<SUB>2</SUB>]<SUP>2+</SUP> forms only a tetracyano complex, but no mixed dicyano complex.<BR>3) [Pd en<SUB>2</SUB>]<SUP>2+</SUP>, [Zn en<SUB>3</SUB>]<SUP>2+</SUP> and [Cd en<SUB>3</SUB>]<SUP>2+</SUP> form dicyano-ethylenediamine complexes in solution.

• 社団法人 日本化学会の論文

著者

• Kida S.

  Department Of Neurosurgery Kanazawa University School Of Medicine

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